Thermal behaviour and isothermal kinetics of rhodium(II) acetate.

Carvalho, Cornélio de FreitasBraga, Mauro MendesYoshida, Maria IreneSinisterra, Ruben Dario2012-10-192012-10-191997BRAGA, M. M. et al. Thermal behaviour and isothermal kinetics of rhodium(II) acetate. Thermochimica Acta, v. 296, p. 141-148, 1997. Disponível em: <https://www.sciencedirect.com/science/article/pii/S004060319700021X>. Acesso em: 19 out. 2012.00406031http://www.repositorio.ufop.br/handle/123456789/1694The thermal decomposition of solid rhodium(II) acetate was studied by isothermal TG. Kinetic analysis of the isothermal data showed that the complex decomposition in the range 198.0-210.5°C occurs according to a Prout-Tompkins (An) law. The isothermal curves are better fitted using a non-linear least square method. The activation energy found was 16:2.7 kJ tool ~. At temperatures higher than 210.5°C the decomposition is strongly accelerated and no kinetic study was available.en-USThermal decompositionIsothermalKineticsMechanismRhodium(II) carboxylatesThermal behaviour and isothermal kinetics of rhodium(II) acetate.Artigo publicado em periodicoO periódico Thermochimica Acta concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença 3313091134473.