Alves, Leandro de CarvalhoRubinger, Mayura Marques MagalhãesLindemann, Renata HernandezPerpétuo, Genivaldo JulioJanczak, JanMiranda, Liany Divina LimaZambolim, LaércioOliveira, Marcelo Ribeiro Leite2015-03-162015-03-162009ALVES, L. C. et al. Syntheses, crystal structure, spectroscopic characterization and antifungal activity of new N-R-sulfonyldithiocarbimate metal complexes. Journal of Inorganic Biochemistry, v. 103, p. 1045-1053, 2009. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0162013409000968>. Acesso em: 20 fev. 2015.0162-0134http://www.repositorio.ufop.br/handle/123456789/4664Five new compounds with the general formula of (Bu4N)2[M(RSO2N@CS2)2], where Bu4N = tetrabutylammonium cation, (M = Ni, R = 4-FC6H4) (1), (M = Zn, R = 4-FC6H4, 4-ClC6H4, 4-BrC6H4, 4-IC6H4), (2), (3), (4) and (5), respectively, were obtained by the reaction of the appropriate potassium N-R-sulfonyldithiocarbimate (RSO2N@CS2K2) with nickel(II) chloride hexahydrate or zinc(II) acetate dihydrate in metanol:water 1:1. The elemental analyses and the IR data are consistent with the formation of the expected bis(dithiocarbimato) metal(II) complexes. The 1H and 13C NMR spectra showed the signals for the tetrabutylammonium cation and the dithiocarbimate moieties. The compounds 1, 2 and 5 were also characterized by X-ray diffraction techniques. The nickel(II) is coordinated by two N-4-fluorophenylsulphonyldithiocarbimato(2-) ligands forming a planar coordination. The zinc(II) exhibits distorted tetrahedral configuration in compounds 2 and 5 due to the chelation effect of two sulfur atoms of the N-R-sulfonyldithiocarbimate ligands. The antifungal activities of the compounds were tested in vitro against Colletotrichum gloeosporioides, an important fungus that causes the plant disease known as anthracnose in fruit trees. All the complexes were active.en-USDithiocarbimatesMetal complexesCrystal structuresAntifungal activityArtigo publicado em periodicoO periódico Journal of Inorganic Biochemistry concede permissão para depósito do artigo no Repositório Institucional da UFOP. Número da licença: 3564801498002.https://doi.org/10.1016/j.jinorgbio.2009.04.018