Oliveira, Marcelo Ribeiro LeitePerpétuo, Genivaldo JulioJanczak, JanRubinger, Mayura Marques Magalhães2015-02-232015-02-232007OLIVEIRA, M. R. L. et al. Synthesis, structural and spectroscopic characterization of novel zinc(II) complexes with N-methylsulfonyldithiocarbimato and N-methylsulfonyltrithiocarbimato ligands. Polyhedron, v. 26, p. 163-168, 2007. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0277538708001149#>. Acesso em: 20 fev. 2015.0277-5387http://www.repositorio.ufop.br/handle/123456789/4464Two new zinc(II)-complexes, dithiocarbimato (Ph4P)2[Zn(CH3SO2N@CS2)2] (1) and trithiocarbimato (Ph4P)2[Zn(CH3SO2N@CS3)2] (2), were obtained in the crystalline form by the reaction of potassium N-methylsulfonyldithiocarbimate (RSO2N@CS2K2) with zinc(II) acetate dihydrate and tetraphenylphosphonium chloride in dimethylformamide. Both complexes crystallize in the monoclinic system. The central Zn(II) ion has a distorted tetrahedral coordination in both compounds. In 1 the dithiocarbimato ligand coordinates via two S atoms while in 2 the trithiocarbimato ligand coordinates via S and N atoms. Both complexes were also characterized by IR, 1H NMR and 13C NMR spectroscopies. Compound 2 is the first example of a zinc(II)-trithiocarbimato complex.en-USDithiocarbimateTrithiocarbimateZinc complexesCrystal structureArtigo publicado em periodicoO periódico Polyhedron concede permissão para depósito do artigo no Repositório Institucional da UFOP. Número da licença: 3564801473075.https://doi.org/10.1016/j.poly.2008.02.030