A bifunctional catalyst based on Nb and V oxides over alumina : oxidative cleavage of crude glycerol to green formic acid.

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dc.contributor.authorOliveira, Henrique dos Santos
dc.contributor.authorOliveira, Luiz Carlos Alves de
dc.contributor.authorChagas, Poliane
dc.contributor.authorSangiorge, Daniel Lara
dc.contributor.authorPortilho, Marcio de Figueiredo
dc.contributor.authorSiqueira, Kisla Prislen Félix
dc.contributor.authorHensen, Emiel J. M.
dc.date.accessioned2021-12-14T16:45:01Z
dc.date.available2021-12-14T16:45:01Z
dc.date.issued2020pt_BR
dc.description.abstractA bimetallic vanadium and niobium oxide catalyst using alumina as support was developed for the conversion of crude glycerol from biodiesel production into formic acid. The high dispersion of the active oxide phase combined with the presence of acid and redox active centers resulted in a high glycerol conversion (490% for 25 h) with a good selectivity for formic acid (B55%). This process is the first example of a heterogeneous liquid-phase process for the conversion of crude glycerol to formic acid, which is an important chemical intermediate currently derived from petroleum feedstock.pt_BR
dc.identifier.citationOLIVEIRA, H, dos S. et al. A bifunctional catalyst based on Nb and V oxides over alumina: oxidative cleavage of crude glycerol to green formic acid. New Journal of Chemistry, v. 44, p. 8538-8544, 2020. Disponível em: <https://pubs.rsc.org/en/content/articlelanding/2020/nj/d0nj00384k>. Acesso em: 10 jun. 2021.pt_BR
dc.identifier.doihttps://doi.org/10.1039/D0NJ00384Kpt_BR
dc.identifier.issn1369-9261
dc.identifier.urihttp://www.repositorio.ufop.br/jspui/handle/123456789/14219
dc.identifier.uri2https://pubs.rsc.org/en/content/articlelanding/2020/nj/d0nj00384kpt_BR
dc.language.isoen_USpt_BR
dc.rightsrestritopt_BR
dc.titleA bifunctional catalyst based on Nb and V oxides over alumina : oxidative cleavage of crude glycerol to green formic acid.pt_BR
dc.typeArtigo publicado em periodicopt_BR

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