EM - Escola de Minas
URI permanente desta comunidadehttp://www.hml.repositorio.ufop.br/handle/123456789/6
Notícias
A Escola de Minas de Ouro Preto foi fundada pelo cientista Claude Henri Gorceix e inaugurada em 12 de outubro de 1876.
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12 resultados
Resultados da Pesquisa
Item Genesis of soils from bauxite in southeastern Brazil : resilication as a soil-forming process.(2017) Mateus, Ana Carolina Campos; Oliveira, Fábio Soares de; Varajão, Angélica Fortes Drummond Chicarino; Soares, Caroline Cibele VieiraPedological studies using X-ray diffraction (XRD), X-ray fluorescence (XRF), optical microscopy, and scanning electron microscopy (SEM-EDS) showed a Xanthic Ferralsol formed from the degradation of bauxite on a slope in the Caparaó region, in southeastern Brazil. We found a decrease in the number and size of bauxite fragments toward the top of the profiles, bauxite fragments that were more degraded at the top of the profiles, transformation of gibbsite into kaolinite, and absolute enrichment in silicon in the mass balance. These indicators suggest that resilication could be the major process responsible for formation of the soil; detailed studies are needed to verify the origin of the silica. The reintroduction of silica into the system occurs by the biogeochemical cycling of vegetation and, in some cases, water table fluctuations, highlighting the role of resilication as a soil-forming process in bauxite-derived soils.Item Kaolinite removal from bauxite by flotation.(2016) Rodrigues, Otávia Martins Silva; Peres, Antônio Eduardo Clark; Henriques, Andréia Bicalho; Amorim, Bárbara GonçalvesThis paper presents a potential condition to separate kaolinite through flotation when it is present in bauxite ore. This research anticipates a Brazilian industry requirement, considering the tendency towards the need for aluminosilicates removal from bauxite ores, as has already occurred in China. Kaolinite is the most abundant aluminosilicate, and gibbsite is the main aluminum bearing mineral in Brazilian bauxite ores. The first step was a fundamental study involving microflotation experiments with pure samples of kaolinite and gibbsite. Ammonium quaternary salts and amines were used as the collector and corn starch as the depressant. In a fundamental study, the best conditions determined in the first step were evaluated for the flotation of kaolinite from bauxite ore using laboratory scale experiments. Tests with AQ142/starch (pH 10) and CTAB (pH 7) led to satisfactory results. In general, the highest values of alumina/silica mass ratio were obtained with AQ142/starch and the highest values of mass recovery and metallurgical recovery were achieved with CTAB.Item Kaolinite microflotation and zeta potential measurements in the presence of ammonium quaternary salts.(2010) Rodrigues, Otávia Martins Silva; Araujo, Armando Corrêa de; Peres, Antônio Eduardo Clark; Alexandrino, Júnia Soares; Lopes, Gilmara MendonçaStudies on kaolinite flotation are being driven by Chinese bauxite characteristics, presenting low alumina:silica weight ratios. This paper addresses the effect of the presence of cetyl pyridine chloride (CPC) and cetyl trimethyl ammonium bromide (CTAB) on kaolinite floatability and zeta potential. The reagents were dosed at three concentrations and the best floatability results were achieved at the highest concentration level (1x10-4 mol/L). Zeta potential determinations showed that both quaternary salts (CPC and CTAB) shift the kaolinite zeta potential to more positive values the specific collectors adsorption onto the mineral surface.Item Mineralogical, micromorphological and geochemical evolution of the kaolin facies deposit from the Capim region (northern Brazil).(2007) Sousa, Daniel José Lima de; Varajão, Angélica Fortes Drummond Chicarino; Jacques, Yvon; Costa, Geraldo Magela daThe Capim Kaolin District (eastern Brazilian Amazon), is one of the largest kaolin deposits in the world; with the kaolin used mainly for paper coating. The kaolin developed at the expense of Cretaceous sandy-clayey sediments of the Ipixuna formation, through intense lateritization from the Mesozoic to Cenozoic times. This work describes the morphological, mineralogical, crystallochemical and geochemical evolution of the Capim kaolin facies. Based on the profile analysis in the open pit fronts, it encompasses X-ray diffraction, thin-section optical analysis, EDS-assisted scanning electron microscopy and transmission electron microscopy, chemical analysis, infrared and Mo¨ssbauer spectroscopies. Six facies were defined as different stages of the supergene process. Ferruginization led to a thick duricrust on the soft kaolin, which in turn evolved from sandy-clayey sediments of the Ipixuna Formation. A subsequent deferruginization event degraded the duricrust, resulting in the flint kaolin facies.Item The relationships between kaolinite crystal properties and the origin of materials for a Brazilian kaolin deposit.(2001) Varajão, Angélica Fortes Drummond Chicarino; Gilkes, Robert J.; Hart, Robert D.The clay particles in a kaolin deposit from Brazil were investigated by X-ray diffraction (XRD), differential thermal analysis (DTA), analytical transmission electron microscopy (ATEM), and electron paramagnetic resonance (EPR) to examine the relationships between morphological and chemical properties of the crystals and to relate these properties to formation conditions. The XRD patterns show the dominant presence of kaolinite with minor amounts of gibbsite, illite, quartz, goethite, hematite, and anatase. ATEM observations show two discontinuities in the deposit as indicated by changes in morphology and size of the kaolinite crystals. At the base of the deposit, hexagonal platy and lath-shaped particles (mean area of 001 face = 0.26 p,m 2) maintain the original fabric of the parent rock which characterizes an in situ evolution. In the middle of the deposit a bimodal population of large (mean area of 001 face > 0.05 ixm:) and small (mean area of 001 face < 0.05 p.m 2) sub-hexagonal platy kaolinite crystals occurs. This zone defines the boundary between the saprolitic kaolinite and the pedogenic kaolinite. Near the top of the profile, laths and irregular plates of kaolinite, together with sub-hexagonal particles, define two different depositional sources in the history of formation of the deposit. Crystal thickness as derived from the width of basal reflections and the Hinckley index are compatible with the morphological results, but show only one discontinuity. At the base of the deposit, kaolinite has a lowdefect density whereas in the middle and at the top of the profile, kaolinite has a high-defect density. Likewise, EPR spectroscopy shows typical spectra of low-defect kaolinite for the bottom of the deposit and typical spectra of high-defect kaolinite for the other portions of the deposit. Despite the morphological changes observed through the profile, the elemental composition of individual kaolinite crystals did not show systematic variations. These results are consistent with the deposit consisting of a transported pedogenic kaolinite over saprolite consisting of in situ kaolinized phyllite.Item A SEM, EDS and vibrational spectroscopic study of the clay mineral fraipontite.(2015) Theiss, Frederick L.; López, Andrés; Cipriano, Ricardo Augusto Scholz; Frost, Ray LeslieThe mineral fraipontite has been studied by using a combination of scanning electron microscopy with energy dispersive analysis and vibrational spectroscopy (infrared and Raman). Fraipontite is a member of the 1:1 clay minerals of the kaolinite-serpentine group. The mineral contains Zn and Cu and is of formula (Cu,Zn,Al)3(Si,Al)2O5(OH)4. Qualitative chemical analysis of fraipontite shows an aluminium silicate mineral with amounts of Cu and Zn. This kaolinite type mineral has been characterised by Raman and infrared spectroscopy; in this way aspects about the molecular structure of fraipontite clay are elucidated.Item Sedimentation and pedogenic features in a clay deposit in Quadrilátero Ferrífero, Minas Gerais, Brazil.(2004) Santos, Maria do Carmo; Varajão, Angélica Fortes Drummond ChicarinoO depósito argiloso do Morro do Caxambu é produto de uma sedimentação Cenozoica sintectônica em um graben de direção NW/SE. Quatro fácies foram identificadas (fragmentária, nodular, maciça e friável) e suas diferenciações são relacionadas a processos gravitacionais de fluxo de massa. A fácies fragmentária é constituída por fragmentos extraclastos do embasamento local Paleoproterozoico e, por grãos quartzosos de granulometria areia dispersos em uma matriz de composição caulinitamuscovita-goethita-hematita. A facies nodular é formada por nódulos litoreliquiais e pedoreliquiais dispersos em uma matriz semelhante à da fácies fragmentária. A fácies maciça é constituída por grãos de quartzo disseminados em uma matriz caulinita-hematita e goethita com traços de muscovita. A fácies friável difere da fácies maciça por sua morfologia em canal, maior conteúdo em quartzo e caulinita e, pela presença de bolas milimétricas de argila. A fácies fragmentária foi depositada durante o estágio inicial de abertura da bacia. Em seguida, sob condições semi-áridas, o escorregamento de materiais lateríticos das encostas circunjacentes levou à formação das facies nodular e maciça. A facies friável foi originada do retrabalhamento dos sedimentos argilosos por fluxos unidirecionais. O aumento em caulinita em direção ao topo da sequência relaciona-se à ação da alteração superficial pósdeposicional.Item Kaolinite and hematite flotation separation using etheramine and ammonium quaternary salts.(2013) Rodrigues, Otávia Martins Silva; Peres, Antônio Eduardo Clark; Martins, Afonso Henriques; Pereira, Carlos AlbertoClay minerals are widespread in various types of mineral deposits. When present, they contribute to the high content of certain parameters such as silica, aluminium, and magnesium. This study aimed to find selectivity windows to separate hematite from a clay mineral (kaolinite) to allow reduction of the levels of silica and alumina in iron ore. The collectors used were: etheramine Flotigam EDA (EDA) and the ammonium quaternary salts: dodecyltrimethylammonium bromide (DTAB) and Tomamine Q-14-2 PG (AQ142). The depressant used was corn starch. The separation selectivity was achieved using DTAB in the pH range between 4 and 10. Using the collectors EDA and AQ142, the selectivity was obtained only in the presence of starch, at pH 10. Laboratory scale tests showed that as far as the particles size is concerned, better selectivity was achieved with finer particles. Circuit configurations including cleaner and scavenger stages, and pilot scale tests, will be required prior to a possible industrial implementation of the separation.Item Estudo comparativo das argilas das olarias dos municípios de Alfenas e Areado, MG.(2012) Gaspar Junior, Lineo Aparecido; Varajão, Angélica Fortes Drummond Chicarino; Souza, Marcos Henrique de Oliveira; Moreno, Maria Margarita TorresOs horizontes pedológicos dos perfis de solos desenvolvidos a partir das rochas pré-cambrianas dos municípios de Alfenas, MG e Areado, MG assim como os sedimentos colúvio-aluvionares associados têm sido intensivamente utilizados para fins cerâmicos (em particular em olarias de tijolos) sem um estudo detalhado para racionalizar sua utilização na indústria cerâmica. Entretanto apesar da proximidade destes dois municípios, segundo antigos trabalhadores das olarias dessas regiões, as argilas do município de Areado têm apresentado qualidade superior às das argilas do município de Alfenas. Tal fato levou ao desenvolvimento do presente trabalho cujo objetivo foi comparar as propriedades mineralógicas (descrição macroscópica e difração de raios X), químicas (elementos maiores por fluorescência por raios X e análise de carbono orgânico) e tecnológicas (distribuição granulométrica de prensagem; granulometria a laser, módulo de ruptura à flexão; absorção de água, porosidade aparente; retração linear de queima; cor de queima, entre outros) das argilas destes dois municípios para se conhecer a matéria-prima dessas duas regiões de modo a desenvolver aplicações tecnológicas adequadas. A melhor qualidade da matéria prima originada do município de Areado (Grupo AR) é devida à maior presença de argilominerais como a caulinita, illita e esmectita associados a uma granulometria mais fina, que contribuiu para uma melhor sinterização.Item Genesis of clayey bodies in Quadrilátero Ferrífero, Minas Gerais, Brazil.(2004) Santos, Marcelo Cabral; Varajão, Angélica Fortes Drummond Chicarino; Yvon, JacquesThis work deals with macromorphological, mineralogical, micromorphological and geochemical studies in clayey bodies from Quadrilátero Ferrı́fero in order to define their genesis and formation conditions in this geologic province from Minas Gerais State. Methodologies, based on the description of outcrops and drill cores, using X-ray diffraction (XRD), differential and gravimetric thermal analyses (DTA-TG), scanning electron microscopy (SEM), optical analysis of thin sections and chemical analyses allowed for the definition of two different genetic types of clayey bodies. One type, SET 1, occurs upon saprolitic material from Paleoproterozoic rocks in unconformity contact. It is constituted, from the base to the top, by four facies: nodular, ferruginous kaolinitic, mottled kaolinitic, and massive kaolinitic. The origin of this set is related to the deposition of lateritic materials by gravitational process. The faciological differentiation of this set is related to the syn-depositional process and postdepositional mechanisms of ferruginization and deferruginization. The second type, SET 2, is composed by an ilmenitic–kaolinitic tabular facies in discordant relationships with the saprolite material from Paleoproterozoic rocks. The origin of this second set is related to “in situ” alteration of intrusive rocks of acidic composition.